After looking through  Chibi-Tom-boy's Journal about her PCA relationships I decided to follow her example which really seemed to help out a lot. So here they are =)
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There is a little bit of changes to the relationships

SOPHOMORE

Independents

Lancelot Robert Pran (M Rhyhorn, 16, Sop.)-Single, kinda looking and yet not looking

Team Blaster

Cody Paden (M Riolu, 17, Jun.)-Taken, with Eva

Eva Aniko Kirsten (F Lugia, 17, Jun.)-Taken, with Cody

Marlene Regina (F Suicune, 17, Jun.) Single

Evander Radovan Takahiro (M Mightyena, 18, Sen.)-Single, not interested in a relationship

Team Flame

John Fray (M Houndoom, 17, Jun.)-dating yohawk's Alice Blackshroud

Scotty Jerome (M Magmar, 17, Jun.)-shows interest in Reiko_Sazanami's Nano Banerjee

Alexa Jasmijn (F Charizard, 17, Sen.)-Single

Carmela Tanis Brighid (F Infernape, 17, Jun.)-Single

Independents

Casey Andi Maura (F Absol, 17, Jun.)-Single, not looking for now

Roxana Josefa http://www.furaffinity.net/view/6229437/ (F Ninetales, 17, Jun.)-Single, unsure

Jessica Ann Takahiro (F Arbok, 17, Jun.)-Single, looking

Carey Ruta Yong (F Honchkrow, 18, Jun.)-Single, not interested in a relationship

Monika Briar (F Salamence, 17, Jun.)-Single

Leoncio Klaas (M Manectric, 17, Jun.)-Single, shows interest in Intruder's Tessa Deutri

Chaz Fridtjof (M Omastar, 17, Jun.)-Single

Tate Tigernán (M Sharpedo, 17, Jun.)-Taken, with xehta13's Lilith Nyx

Lyle Auguste (M Noctowl, 17, Jun.)-Single, not really sure

Celia Cristina (F Milotic, 17, Jun.)-Single, wouldn't mind having her special someone

Leo Theodor (M Alakazam, 17, Jun.)-Taken, dating belker's Azure

Lino Lawson (M Glalie, 17, Jun.)-Single, unsure at the moment

Derick Zheng (M Gabite, 17, Jun.)-Single, kinda looking

Umi Vaporeon http://www.furaffinity.net/view/6185968/ (F Vaporeon, 17 Jun.)- Single, not really looking

Helena http://www.furaffinity.net/view/6186622/ (F Butterfree, 17, Jun.)-Single, not really looking

Independents

Rei Yuki Shanna (F Golduck, 18, Sen.)-Single, looking

Jacob Rolo (M Sandslash, 18, Sen.)-Single, seems to show interest in slipe's Sidney

Tia Patricia Cynthia (F Swellow, 18, Sen.)-Single

Conor Rein (M Crobat, 17, Sen.)-Taken, with pokeforce's Maya

Greger Tibor Sabas (M Sneasel, 18, Sen.)-Single

Mélissa Alazne (F Raichu, 18, Sen.)-Single, unsure

Orlando Aníbal (M Luxray. 18, Sen.)-Single, unsure

Regina Tomoko (F Dragonair, 18, Sen.)-Single

Brandon Cleto (M Floatzel, 18, Sen.)-Single

Márcio Stuart (M Haunter, 18, Sen.)-Single, somewhat looking

Jadyn Amhlaidh (M Rhydon, 18, Sen.)-Single, not sure yet

Jed Dyson http://www.furaffinity.net/view/6196055/ (M Rayquaza, 18, Sen.)-Single, kinda looking

Pepper Hua http://www.furaffinity.net/view/6196076/ (F Bayleaf, 18, Sen.)-Single, but has a small crush on a Haunter.

Miang-Wa-Long http://www.furaffinity.net/view/6196252/ (M Primeape, 18, Sen.)-Single, not sure

Ada Charley (F Alakazam, 18, Sen.)-Single, not really looking

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Alice Blackshroud ©  yohawk

Nano Baerjee ©  Reiko_Sazanami

Tessa Deutri ©  Intruder

Sidney ©  slipe

Lilith Nyx ©  xehta13

Maya ©  pokeforce

Azure ©  belker