Sometime in the near future(hopefully just a week) I'll be purchasing the Elgato Game Capture HD, http://www.elgato.com/gaming/game-capture-hd ,
and will be doing my first ever LP/stream but I have no clue as to what I'll play first. So I'll be listing off all my games, Downloaded titles and most RPGs excluded for now.

PS1

Broken Sword II: The Smoking Mirror
Croc: Legend of the Gobbos
Dracula: The Last Sanctuary
Heart of Darkness
Legacy of Kain: Soul Reaver
Nightmare Creatures
Resident Evil 2: DualShock
Silent Hill

PS2

Beyond Good and Evil
Clock Tower 3
Cold Fear
Dirge of Cerberus - Final Fantasy VII
Drakan: The Ancient Gates
Evil Dead: Regeneration
Extermination ***UPDATE***
Fatal Frame
Fatal Frame II
Fatal Frame III: Crimson Butterfly
Half-Life
Haunting Ground
Indigo Phrofecy
Klonoa 2: Lunatea's Veil ***UPDATE***
Legend of Spyro: A New Beginning
Legend of Spyro: The Eternal Night
M.D.K. 2: Armageddon
Onimusha ***UPDATE***
Primal ***UPDATE***
Raiden III
Resident Evil: Code Veronica X
Resident Evil: Dead Aim
Return to Castle Wolfenstein: Operation Resurrection
Scaler
Silent Hill 2
Spyro: Enter the Dragonfly
Spyro: A Heroes Tail
The Thing
X-Files: Resist or Serve

PS3

3D Dot Game Heroes
Asura's Wrath
Batman: Arkham Asylum
Batman: Arkham City
Borderlands
Borderlands 2
Bulletstorm
Deadpool
Dead Space
Dead Space 2
Dead Space 3
Deus Ex: Human Revolution
Doom 3: BFG Edition
Duck Tales Remastered
Elder Scrolls V: Skyrim Legendary
Heavy Rain
Infamous
Infamous 2
Jak and Daxter Collection
Killzone 3
Legend of Spyro: Dawn of the Dragon
Mass Effect 2
Mass Effect 3
Nier
Ratchet and Clank Collection
Ratchet and Clank Future: Tools of Destruction
Ratchet and Clank Future: A Crack in Time
Ratchet and Clank: All 4 One
Ratchet and Clank: Full Frontal Assault
Ratchet and Clank: Into the Nexus
Red Dead Redemption
Red Faction: Armageddon
Resident Evil 6
Resident Evil: Operation Raccoon City
Resistance: Fall of Man
Resistance 2
Resistance 3
Silent Hill: HD Collection
Silent Hill: Downpour
Sonic's ultimate Genesis Collection
Sly Collection
Tomb Raider
Uncharted: Darkes Fortune
Uncharted 2: Among Thieves
Uncharted 3: Drakes Deception
Watchmen: The End is Nigh

WiiU

Nintendoland
New Super Mario 3D World

Wii

Dragon's Lair Trilogy
Kirby's Dream Collection
LEGO Harry Potter: Years 1-4
Metroid Prime 3: Corruption
Pandora's Tower
Silent Hill: Shattered Memories
Super Mario Galaxy
Super Paper Mario
Wario Land: Shake It!

Please give your suggestions, you can either just list off the title(s) or give a compelling argument for why I should play it/them. I haven't played most of these titles so good chance whatever is chosen I'll explore for the first time.